Tuesday, December 13, 2011

How to Buy Polyethylene

Polyethylene is a solid  with its melting point  92 °C and freezing point 270 °C. It is stable, but breaks down slowly in uv light or sunlight ,incompatible with halogens, strong oxidizing agents, benzene, petroleum ether, aromatic and chlorinated hydrocarbons, lubricating oils. CAS: 9002-88-4. Polyethylene or polythene (IUPAC name polyethene or poly(methylene)) is the most widely used plastic, with an annual production of approximately 80 million metric tons. Its primary use is within packaging (notably the plastic shopping bag). Molecular Formula: [C2H4]n. This is the polymer that makes grocery bags, shampoo bottles, children's toys, and even bullet proof vests. For such a versatile material, it has a very simple structure, the simplest of all commercial polymers.
Polyethylene is probably the polymer you see most in daily life. Polyethylene is the most popular plastic in the world. A molecule of polyethylene is nothing more than a long chain of carbon atoms, with two hydrogen atoms attached to each carbon atom. That's what the picture at the top of the page shows. Thus, the alternate form, poly(ethylene terephthalate), is often used in scholarly journals for the sake of accuracy and clarity. Sometimes it's a little more complicated. Sometimes some of the carbons, instead of having hydrogens attached to them, will have long chains of polyethylene attached to them. The semicrystalline material might appear transparent (particle size < 500 nm) or opaque and white (particle size up to a few microns) depending on its crystal structure and particle size. Its monomer (bis-β-hydroxyterephthalate) can be synthesized by the esterification reaction between terephthalic acid and ethylene glycol with water as a byproduct, or by transesterification reaction between ethylene glycol and dimethyl terephthalate with methanol as a byproduct. This is called branched, or low-density polyethylene, or LDPE. When there is no branching, it is called linear polyethylene, or HDPE. Linear polyethylene is much stronger than branched polyethylene, but branched polyethylene is cheaper and easier to make.
Polyethylene is a thermoplastic polymer consisting of long chains produced by combining the ingredient monomer ethylene (IUPAC name ethene), the name comes from the ingredient and not the actual chemical resulting.
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